03569nam a22001817a 4500 OSt 20251106131108.0 251007b |||||||| |||| 00| 0 eng d 9780444822543 KUL 547.788 KAM/C Kamide, K 2697 Cellulose and Cellulose Derivatives Molecular Characterization and its Applications Amsterdam: Elsevier, 2005. xx, 630p.: Introduction1.1 Cellulose: The Most Abundant Natural Organic Compound1.2 New Era of Cellulose Derivatives as Artificial Materials in Middle 19th Century: Cellulose Chemical Industries 1.3 Emergence of Polymer Science in 1920s 1.4 Further Development of Molecular Characterization of Cellulose and Cellulose Derivatives during 1940s-1970s 1.5 Solved and Unsolved Problems in Molecular Characterization of Cellulose Derivatives in 1970's Characterization of Molecular Structure of Cellulose Derivatives 2.1 Definitions of Molecular Structure Parameters 2.2 Total Degree of Substitution(DS) 2.3 Determination of Substituent Group among Three Hydroxyl Groups in Glucopyranose Unit 2.4 Molar Fraction of 8 kinds of Unsubstituted and Partially or Fully Substituted Glucopyranose Units 2.5 Thin-Layer Chromatography(TLC) 2.6 Sequence Distribution of Substituted and Unsubstituted Glucopyranose Units in Water-Soluble Cellulose Acetate Chain as Revealed by Enzymatic Degradation 2.7 Sodium Cellulose Sulfate as Blood Anti-coagulant 2.8 Sodium Salt of Carboxymethylcellulose as Absorbent towards Aqueous Liquid 2.9 Ripening of Viscose 2.10 Thermal Properties of Cellulose Acetate Solid 2.11 Surface Activity of Aqueous Solution of Cellulose Acetate Molecular Properties of Cellulose and Cellulose Derivatives 3.1 Sample Preparation 3.2 Fractionation 3.3 Membrane Osmometry(MO) 3.4 Vapor Pressure Osmometry(VPO)3.5 Light Scattering(LS) 3.6 Viscometry 3.7 Sedimentation velocity 3.8 Adiabatic compressibility 3.9 Nuclear Magnetic Resonance Study of Thermodynamic Interaction 3.10 Small Angle X-ray Scattering (SAXS)3.11 Mark-Houwink-Sakurada (MHS) Equations 3.12 Molecular Weight Dependence of Radius of Gyration 3.13 Second Virial Coefficient and Excluded Volume Effect 3.14 Molecular Weight Dependence of Sedimentation and Diffusion Coefficients 3.15 Flory Viscosity Parameter and Partial Draining Effect 3.16 Unperturbed Chain Dimensions(UCD) 3.17 Solvation 3.18 Effect of Solvent Nature and Total Degree of Substitution 3.19 Persistence 3.20 Temperature Dependence of Limiting Viscosity Number and Radius of Gyration 3.21 Phase Separation : Cloud Point Curve and Flory Theta Solvents 3.22 Concluding Remarks on Molecular Properties of Cellulose Chain 3.23 Cellulose Liquid 3.24 Preparation of Porous Cellulose Membrane by Phase-Separation Method: Phenomenological Effects of Solvent-Casting Conditions on Pore Characteristic Cellulose in Aq Sodium Hydroxide 4.1 Solubility of Cellulose in Aq Alkali Solution 4.2 Intramolecular Hydrogen Bonds and Selective Coordination of Alkali Cellulose 4.3 Some Characteristic Features of Dilute Aqueous Alkali Solution 4.4 Structural Change in Cellulose Solid During its Dissolution into Aq Alkali4.5 Flow Birefringence and Viscosity 4.6 Gels of Cellulose ~ Aqueous Alkali System 4.7 Cellulose Fibers and Films Wet-Spun from Cellulose ~ Aq Alkali Solution Solubilization, Structural Factors Governing Solubility and Dissolved State 5.1 Solubilization of Cellulose by Steam Explosion Method 5.2 Structural Factors Governing Dissolution into Solvents 4307 ddc BK 752091 752091 0 0 ddc 0 0 DOP DOP NEW 2025-10-07 0 547.788 KAM/C DOP3745 2025-10-07 08:10:50 2025-10-07 REF Reference Only