000			01494nam a22001697a 4500
020			_a9789391096724
082			_a541.39 _bILY/R
100			_aIlyas,Shahla
245			_aReaction Mechanism of Organometallic Systems/ _cby Shahla Ilyas
260			_aNew Delhi: _bOxford Book Company, _c2022.
300			_aviii,264p.
505			_a1.Rate Law and Mechanism-- 2.Principles of Chemical Dynamics-- 3.Steriochemical Change-- 4.Ligand Substitution Reactions-- 5.Oxidation -Reduction Reaction-- 6.Inorganic Photochemistry.
520			_aThe study of Reaction Mechanism of Organometallic Systems is presented. The primary mechanistic types discussed are ligand substitution, oxidative addition, reductive elimination, and electron transfer. Each reaction pathway is discussed within the context of the common electron counts encountered for most organometallic complexes. Examples of how these common reaction pathways extend to polynuclear complexes are also presented. Although reasonable generalizations with regard to overall reaction rates and stepwise mechanisms using the electron count formalism can be made, many recent reports point out that the details of ligand and metal center structure can override these general trends. A considerable amount of quantitative rate data is provided and computational methodologies for understanding the observed rates are discussed.
650			_aOrganometallic compounds--Reactivity
650			_aReaction mechanisms (Chemistry)
942			_cBK
999			_c672019 _d672019